"replaced, such as sulfur dioxide. Haloalkanes are also an order(s) of magnitude more expensive than petroleum derived flammable alkanes of similar or better cooling performance. Unfortunately, chlorine- and fluorine-bearing refrigerants reach the upper atmosphere when they escape. In the stratosphere, CFCs break up due to UV radiation, releasing their chlorine free radicals. These chlorine free radicals act as catalysts in the breakdown of ozone through chain reactions. One CFC molecule can cause thousands of ozone molecules to break down. This causes severe damage to the ozone layer that shields the Earth's surface from the Sun's strong UV radiation, and has"
"28, 2003, which operated until early 2012. Ozone layer The Ozone layer or ozone shield is a region of Earth's stratosphere that absorbs most of the Sun's ultraviolet radiation. It contains high concentrations of ozone (O) in relation to other parts of the atmosphere, although still small in relation to other gases in the stratosphere. The ozone layer contains less than 10 parts per million of ozone, while the average ozone concentration in Earth's atmosphere as a whole is about 0.3 parts per million. The ozone layer is mainly found in the lower portion of the stratosphere, from approximately above"
"Ozone layer The Ozone layer or ozone shield is a region of Earth's stratosphere that absorbs most of the Sun's ultraviolet radiation. It contains high concentrations of ozone (O) in relation to other parts of the atmosphere, although still small in relation to other gases in the stratosphere. The ozone layer contains less than 10 parts per million of ozone, while the average ozone concentration in Earth's atmosphere as a whole is about 0.3 parts per million. The ozone layer is mainly found in the lower portion of the stratosphere, from approximately above Earth, although its thickness varies seasonally and"
"The lowest layer is the troposphere, which extends from the surface to the bottom of the stratosphere. Three quarters of the atmosphere's mass resides within the troposphere, and is the layer within which the Earth's terrestrial weather develops. The depth of this layer varies between 17 km at the equator to 7 km at the poles. The stratosphere, extending from the top of the troposphere to the bottom of the mesosphere, contains the ozone layer. The ozone layer ranges in altitude between 15 and 35 km, and is where most of the ultraviolet radiation from the Sun is absorbed. The"
"changed height in phase with solar activity during solar cycles 20–23. UV irradiance increase caused higher ozone production, leading to stratospheric heating and to poleward displacements in the stratospheric and tropospheric wind systems. With a temperature of 5870 K, the photosphere emits a proportion of radiation in the extreme ultraviolet (EUV) and above. However, hotter upper layers of the Sun's atmosphere (chromosphere and corona) emit more short-wavelength radiation. Since the upper atmosphere is not homogeneous and contains significant magnetic structure, the solar ultraviolet (UV), EUV and X-ray flux varies markedly over the cycle. The photo montage to the left illustrates"
"The ozone layer (which absorbs from about 200 nm to 310 nm with a maximal absorption at about 250 nm) is very effective at screening out UV-B; for radiation with a wavelength of 290 nm, the intensity at the top of the atmosphere is 350 million times stronger than at the Earth's surface. Nevertheless, some UV-B, particularly at its longest wavelengths, reaches the surface, and is important for the skin's production of vitamin D. Ozone is transparent to most UV-A, so most of this longer-wavelength UV radiation reaches the surface, and it constitutes most of the UV reaching the Earth."
"spots and noticeable seasonal changes. (see below) The stratosphere is the middle layer of the Uranian atmosphere, in which temperature generally increases with altitude from 53 K in the tropopause to between 800 and 850 K at the base thermosphere. The heating of the stratosphere is caused by the downward heat conduction from the hot thermosphere as well as by absorption of solar UV and IR radiation by methane and the complex hydrocarbons formed as a result of methane photolysis. The methane enters the stratosphere through the cold tropopause, where its mixing ratio relative to molecular hydrogen is about 3,"
"stratosphere was discovered to be declining, mostly because of increasing concentrations of chlorofluorocarbons (CFC) and similar chlorinated and brominated organic molecules. The concern over the health effects of the decline led to the 1987 Montreal Protocol, the ban on the production of many ozone depleting chemicals and in the first and second decade of the 21st Century the beginning of the recovery of stratospheric ozone concentrations. Ozone in the ozone layer filters out sunlight wavelengths from about 200 nm UV rays to 315 nm, with ozone peak absorption at about 250 nm. This ozone UV absorption is important to life,"
"(160 to 400 nm). The SBUV is capable of determining the global ozone concentration in the stratosphere to an absolute accuracy of 1 percent; the vertical distribution of atmospheric ozone to an absolute accuracy of 5 percent; the long-term solar spectral irradiance from 160 to 400 nm Photochemical process and the influence of “trace” constituents on the ozone layer. The Ball Aerospace-built SBUV/2 helped to discover the ozone hole over Antarctica in 1987, and continues to monitor this phenomenon. Atmospheric ozone absorbs the sun’s ultraviolet rays, which are believed to cause gene mutations, skin cancer, and cataracts in humans. Ultraviolet"
"radiation (emitted by the sun) and terrestrial radiation (emitted by Earth's surface and atmosphere). Solar radiation contains variety of wavelengths. Visible light has wavelengths between 0.4 and 0.7 micrometers. Shorter wavelengths are known as the ultraviolet (UV) part of the spectrum, while longer wavelengths are grouped into the infrared portion of the spectrum. Ozone is most effective in absorbing radiation around 0.25 micrometers, where UV-c rays lie in the spectrum. This increases the temperature of the nearby stratosphere. Snow reflects 88% of UV rays, while sand reflects 12%, and water reflects only 4% of incoming UV radiation. The more glancing"
"often at great depths below the skin, since the higher end of the X-ray spectrum, and all of the gamma ray spectrum, penetrate matter. Most UV and X-rays are blocked by absorption first from molecular nitrogen, and then (for wavelengths in the upper UV) from the electronic excitation of dioxygen and finally ozone at the mid-range of UV. Only 30% of the Sun's ultraviolet light reaches the ground, and almost all of this is well transmitted. Visible light is well transmitted in air, as it is not energetic enough to excite nitrogen, oxygen, or ozone, but too energetic to excite"
"substances (ODS). These compounds are transported into the stratosphere by the winds after being emitted from the surface. Once in the stratosphere, they release halogen atoms through photodissociation, which catalyze the breakdown of ozone (O) into oxygen (O). Both types of ozone depletion were observed to increase as emissions of halocarbons increased. Ozone depletion and the ozone hole have generated worldwide concern over increased cancer risks and other negative effects. The ozone layer prevents most harmful UVB wavelengths of ultraviolet light (UV light) from passing through the Earth's atmosphere. These wavelengths cause skin cancer, sunburn and cataracts, which were projected"
"are absorbed by nitrogen and, at longer wavelengths, by simple diatomic oxygen in the air. Most of the UV in the mid-range of energy is blocked by the ozone layer, which absorbs strongly in the important 200–315 nm range, the lower energy part of which is too long for ordinary dioxygen in air to absorb. This leaves less than 3% of sunlight at sea level in UV, with all of this remainder at the lower energies. The remainder is UV-A, along with some UV-B. The very lowest energy range of UV between 315 nm and visible light (called UV-A) is"
"layer. In the stratosphere, ozone is continuously regenerated by the splitting of O molecules by ultraviolet light. During a solar minimum, the decrease in ultraviolet light received from the Sun leads to a decrease in the concentration of ozone, allowing increased UVB to reach the Earth's surface. Skywave modes of radio communication operate by bending (refracting) radio waves (electromagnetic radiation) through the Ionosphere. During the ""peaks"" of the solar cycle, the ionosphere becomes increasingly ionized by solar photons and cosmic rays. This affects the propagation of the radio wave in complex ways that can either facilitate or hinder communications. Forecasting"
"Antarctica. The ionosphere is a shell of electrons and electrically charged atoms and molecules that surrounds the Earth, stretching from a height of about to more than . It exists primarily due to ultraviolet radiation from the Sun. The lowest part of the Earth's atmosphere, the troposphere extends from the surface to about . Above that is the stratosphere, followed by the mesosphere. In the stratosphere incoming solar radiation creates the ozone layer. At heights of above , in the thermosphere, the atmosphere is so thin that free electrons can exist for short periods of time before they are captured"
"in 1990. This change in the law reflected significant changes in scientific understanding of ozone formation and depletion. Ozone absorbs UVC light and shorter wave UVB, and lets through UVA, which is largely harmless to people. Ozone exists naturally in the stratosphere, not the troposphere. It is laterally distributed because it is destroyed by strong sunlight, so there is more ozone at the poles. Ozone is created when O comes in contact with photons from solar radiation. Therefore, a decrease in the intensity of solar radiation also results in a decrease in the formation of ozone in the stratosphere. This"
"is on average , reaching to as high as in the narrow layers in the stratosphere. The ionosphere is mainly sustained by solar UV radiation and its density depends on the solar activity. The auroral activity on Uranus is not as powerful as at Jupiter and Saturn and contributes little to the ionization. The high electron density may be in part caused by the low concentration of hydrocarbons in the stratosphere. One of the sources of information about the ionosphere and thermosphere comes from ground-based measurements of the intense mid-infrared (3–4 μm) emissions of the trihydrogen cation (). The total"
"Thermosphere The thermosphere is the layer of the Earth's atmosphere directly above the mesosphere and below the exosphere. Within this layer of the atmosphere, ultraviolet radiation causes photoionization/photodissociation of molecules, creating ions in the ionosphere. Taking its name from the Greek θερμός (pronounced ""thermos"") meaning heat, the thermosphere begins at about 80 km (50 mi) above sea level. At these high altitudes, the residual atmospheric gases sort into strata according to molecular mass (see turbosphere). Thermospheric temperatures increase with altitude due to absorption of highly energetic solar radiation. Temperatures are highly dependent on solar activity, and can rise to 1,700"
"of the ionospheric plasma and causes therefore a decrease of the electron density within the ionospheric F-layer (negative ionospheric storm). Thermosphere The thermosphere is the layer of the Earth's atmosphere directly above the mesosphere and below the exosphere. Within this layer of the atmosphere, ultraviolet radiation causes photoionization/photodissociation of molecules, creating ions in the ionosphere. Taking its name from the Greek θερμός (pronounced ""thermos"") meaning heat, the thermosphere begins at about 80 km (50 mi) above sea level. At these high altitudes, the residual atmospheric gases sort into strata according to molecular mass (see turbosphere). Thermospheric temperatures increase with altitude"
"in the range of , ammonia or hydrogen sulfide clouds at between and finally directly detected thin methane clouds at . The troposphere is a dynamic part of the atmosphere, exhibiting strong winds, bright clouds and seasonal changes. The middle layer of the Uranian atmosphere is the stratosphere, where temperature generally increases with altitude from in the tropopause to between at the base of the thermosphere. The heating of the stratosphere is caused by absorption of solar UV and IR radiation by methane and other hydrocarbons, which form in this part of the atmosphere as a result of methane photolysis."
"stratosphere, where it is easily broken down (photolyzed) by ultraviolet radiation (UV). Heating of the upper atmosphere by UV radiation can then drive a hydrodynamic wind that carries the hydrogen (and potentially some of the oxygen) to space, leading to the irreversible loss of a planet's surface water, oxidation of the surface, and possible accumulation of oxygen in the atmosphere. The fate of a given planet's atmosphere strongly depends on the extreme ultraviolet flux, the duration of the runaway regime, the initial water content, and the rate at which oxygen is absorbed by the surface. Volatile-rich planets should be more"
"level sunlight is 44% visible light, 3% ultraviolet (with the Sun at its zenith), and the remainder infrared. Thus, the atmosphere blocks about 77% of the Sun's UV, almost entirely in the shorter UV wavelengths, when the Sun is highest in the sky (zenith). Of the ultraviolet radiation that reaches the Earth's surface, more than 95% is the longer wavelengths of UVA, with the small remainder UVB. There is essentially no UVC. The fraction of UVB which remains in UV radiation after passing through the atmosphere is heavily dependent on cloud cover and atmospheric conditions. Thick clouds may block up"
"in a cooling effect in the stratosphere. If the sun was responsible for observed warming, warming of the troposphere at the surface and warming at the top of the stratosphere would be expected as increase solar activity would replenish ozone and oxides of nitrogen. The stratosphere has a reverse temperature gradient than the troposphere so as the temperature of the troposphere cools with altitude, the stratosphere rises with altitude. Hadley cells are the mechanism by which equatorial generated ozone in the tropics (highest area of UV irradiance in the stratosphere) is moved poleward. Global climate models suggest that climate change"
"calls Earth's atmosphere ""a delicate cocoon of air that shields us from our star's radiation."" Of course, the atmosphere doesn't completely block electromagnetic radiation from the Sun; without some sunlight reaching the surface, plants could not harvest the Sun's energy, and practically no life as we know it could exist. The atmosphere's ozone layer does filter out much of the harmful ultraviolet light (or ""UV rays"") produced by the Sun. UV rays can cause skin cancer, and catastrophic damage to the ozone layer may have contributed to Earth's most extensive mass extinction of species ever, the End-Permian extinction (also known"
"hemisphere, November, December and January. On a minute-by-minute basis, the amount of UV radiation is dependent on the angle of the sun. This is easily determined by the height ratio of any object to the size of its shadow. The greatest risk is at solar noon, when shadows are at their minimum and the sun's radiation passes most directly through the atmosphere. Regardless of one's latitude (assuming no other variables), equal shadow lengths mean equal amounts of UV radiation. The skin and eyes are most sensitive to damage by UV at 265–275 nm wavelength, which is in the lower UVC"
"by ozone (O) in particular. Ionizing UV therefore does not penetrate Earth's atmosphere to a significant degree, and is sometimes referred to as vacuum ultraviolet. Although present in space, this part of the UV spectrum is not of biological importance, because it does not reach living organisms on Earth. There is a zone of the atmosphere in which ozone absorbs some 98% of non-ionizing but dangerous UV-C and UV-B. This so-called ozone layer starts at about and extends upward. Some of the ultraviolet spectrum that does reach the ground (the part that begins above energies of 3.1 eV, a wavelength"
"the risk of sunburn increases with proximity to the tropic latitudes, located between 23.5° north and south latitude. All else being equal (e.g., cloud cover, ozone layer, terrain, etc.), over the course of a full year, each location within the tropic or polar regions receives approximately the same amount of UV radiation. In the temperate zones between 23.5° and 66.5°, UV radiation varies substantially by latitude and season. The higher the latitude, the lower the intensity of the UV rays. Intensity in the northern hemisphere is greatest during the months of May, June and July — and in the southern"
"called the ozone-oxygen cycle. Chemically, this can be described as: About 90 percent of the ozone in the atmosphere is contained in the stratosphere. Ozone concentrations are greatest between about , where they range from about 2 to 8 parts per million. If all of the ozone were compressed to the pressure of the air at sea level, it would be only thick. Although the concentration of the ozone in the ozone layer is very small, it is vitally important to life because it absorbs biologically harmful ultraviolet (UV) radiation coming from the sun. Extremely short or vacuum UV (10–100"
"see is produced as electrons react with hydrogen atoms to produce H ions. The photosphere is tens to hundreds of kilometers thick, and is slightly less opaque than air on Earth. Because the upper part of the photosphere is cooler than the lower part, an image of the Sun appears brighter in the center than on the edge or ""limb"" of the solar disk, in a phenomenon known as limb darkening. The spectrum of sunlight has approximately the spectrum of a black-body radiating at 5,777 K, interspersed with atomic absorption lines from the tenuous layers above the photosphere. The photosphere"
"sulfide in the deep atmosphere are poorly known. They are probably also higher than solar values. Along with methane, trace amounts of various hydrocarbons are found in the stratosphere of Uranus, which are thought to be produced from methane by photolysis induced by the solar ultraviolet (UV) radiation. They include ethane (), acetylene (), methylacetylene (), and diacetylene (). Spectroscopy has also uncovered traces of water vapour, carbon monoxide and carbon dioxide in the upper atmosphere, which can only originate from an external source such as infalling dust and comets. The troposphere is the lowest and densest part of the"
"radiation on skin cells, which is the main cause of skin cancer. UV rays in the middle range can irreparably damage the complex DNA molecules in the cells producing thymine dimers making it a very potent mutagen. The Sun emits significant UV radiation (about 10% of its total power), including extremely short wavelength UV that could potentially destroy most life on land (ocean water would provide some protection for life there). However, most of the Sun's damaging UV wavelengths are absorbed by the atmosphere before they reach the surface. The higher energy (shortest wavelength) ranges of UV (called ""vacuum UV"")"
"Ionosphere The ionosphere () is the ionized part of Earth's upper atmosphere, from about to altitude, a region that includes the thermosphere and parts of the mesosphere and exosphere. The ionosphere is ionized by solar radiation. It plays an important role in atmospheric electricity and forms the inner edge of the magnetosphere. It has practical importance because, among other functions, it influences radio propagation to distant places on the Earth. As early as 1839, the German mathematician and physicist Carl Friedrich Gauss postulated that an electrically conducting region of the atmosphere could account for observed variations of Earth's magnetic field."
"Ionosphere The ionosphere () is the ionized part of Earth's upper atmosphere, from about to altitude, a region that includes the thermosphere and parts of the mesosphere and exosphere. The ionosphere is ionized by solar radiation. It plays an important role in atmospheric electricity and forms the inner edge of the magnetosphere. It has practical importance because, among other functions, it influences radio propagation to distant places on the Earth. As early as 1839, the German mathematician and physicist Carl Friedrich Gauss postulated that an electrically conducting region of the atmosphere could account for observed variations of Earth's magnetic field."